Activation of olefins with low-valent gallium compounds under ambient conditions.

نویسندگان

  • Christine A Caputo
  • Zhongliang Zhu
  • Zachary D Brown
  • James C Fettinger
  • Philip P Power
چکیده

The reactions of Ar'GaGaAr' (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-(i)Pr(2))(2)) with alkenes revealed the addition of two olefins per Ar'GaGaAr' under ambient conditions for ethylene, propene, 1-hexene and styrene but no reactions with more hindered or cyclic olefins.

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عنوان ژورنال:
  • Chemical communications

دوره 47 26  شماره 

صفحات  -

تاریخ انتشار 2011